Aqueous-phase NADH regeneration using Rh(N-heterocyclic carbene) catalyst with enhanced hydride kinetics

A new [Cp*Rh(NHC–pyridyl)Cl] + complex enables rapid, selective aqueous NADH regeneration via accelerated Rh–H formation, revealing ligand-controlled hydride kinetics and mechanistic links between structure and activity.

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Publication Details

Journal
Inorganic Chemistry Frontiers
Published
2025-11-03
DOI
https://doi.org/10.1039/d5qi01887k
Primary Topic
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
Type
article
Field-Weighted Citation Impact
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article

Aqueous-phase NADH regeneration using Rh(N-heterocyclic carbene) catalyst with enhanced hydride kinetics

Inorganic Chemistry Frontiers
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
article

Aqueous-phase NADH regeneration using Rh(N-heterocyclic carbene) catalyst with enhanced hydride kinetics

article en

Abstract

A new [Cp*Rh(NHC–pyridyl)Cl] + complex enables rapid, selective aqueous NADH regeneration via accelerated Rh–H formation, revealing ligand-controlled hydride kinetics and mechanistic links between structure and activity.

Inorganic Chemistry FrontiersVol. 13(2)
Korea Atomic Energy Research Institute (KR), Chung-Ang University (KR)
Clean water and sanitation
Openalex Percentile: Top 44%
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
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Aqueous-phase NADH regeneration using Rh(N-heterocyclic carbene) catalyst with enhanced hydride kinetics · Inorganic Chemistry Frontiers (2025) | TGRS Research Map | TGRS