Cobalt-catalyzed cross-electrophile coupling of aryl bromides and linear secondary alkyl bromides

An efficient cobalt-catalyzed cross-electrophile coupling (XEC) reaction of aryl halides with linear secondary alkyl halides to construct C(sp 3 )–C(aryl) motif was reported. The key to the reaction is the use of a phosphino-oxazoline (PHOX) ligand.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-10-24
DOI
https://doi.org/10.1039/d5qo01310k
Primary Topic
Neurology and Historical Studies
Type
article
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article

Cobalt-catalyzed cross-electrophile coupling of aryl bromides and linear secondary alkyl bromides

Organic Chemistry Frontiers
Neurology and Historical Studies
article

Cobalt-catalyzed cross-electrophile coupling of aryl bromides and linear secondary alkyl bromides

article en

Abstract

An efficient cobalt-catalyzed cross-electrophile coupling (XEC) reaction of aryl halides with linear secondary alkyl halides to construct C(sp 3 )–C(aryl) motif was reported. The key to the reaction is the use of a phosphino-oxazoline (PHOX) ligand.

Organic Chemistry FrontiersVol. 13(2)
Wuhan University (CN)
Clean water and sanitation
Openalex Percentile: Top 44%
Neurology and Historical Studies
DOISourceOpenAlex
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Cobalt-catalyzed cross-electrophile coupling of aryl bromides and linear secondary alkyl bromides · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS