Mechanistic insights into NHC/Cu catalyzed asymmetric synthesis of spirooxindoles: origins of enantioselectivity and diastereoselectivity

This work elucidates the NHC/Cu-catalyzed asymmetric annulation of isatin-derived enals with ethynyl carbonates, uncovering the origins of high stereo-selectivity and highlighting the crucial role of water molecules in catalysis.

Institutions

Nanjing Tech University (CN)

Publication Details

Journal: Organic Chemistry Frontiers
Published: 2025-10-07
DOI: https://doi.org/10.1039/d5qo01235j
Primary Topic: Photovoltaic Systems and Sustainability
Type: article
Field-Weighted Citation Impact: 0.00

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article

Mechanistic insights into NHC/Cu catalyzed asymmetric synthesis of spirooxindoles: origins of enantioselectivity and diastereoselectivity

Oct 7, 2025

Organic Chemistry Frontiers

Photovoltaic Systems and Sustainability

article

Mechanistic insights into NHC/Cu catalyzed asymmetric synthesis of spirooxindoles: origins of enantioselectivity and diastereoselectivity

October 7, 2025article en

Abstract

Organic Chemistry FrontiersVol. 13(1)

Nanjing Tech University (CN)

Clean water and sanitation

Openalex Percentile: Top 51%

Photovoltaic Systems and Sustainability

DOI Source OpenAlex

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Mechanistic insights into NHC/Cu catalyzed asymmetric synthesis of spirooxindoles: origins of enantioselectivity and diastereoselectivity · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS