The Hungry Daemon: Does an Energy-Harvesting Active Particle Have to Obey the Second Law of Thermodynamics?

Thought experiments like Maxwell’s Demon or the Smoluchowski–Feynman Ratchet can help in pursuing the microscopic origin of the Second Law of Thermodynamics. Here we present a more sophisticated mechanical system than a ratchet, consisting of a Hamiltonian (non-Brownian) active particle which can harvest energy from an environment which may be in thermal equilibrium at a single temperature. We show that while a phenomenological description would seem to allow the system to operate as a Perpetual Motion Machine of the Second Kind, a full mechanical analysis confirms that this is impossible, and that perpetual energy harvesting within a mechanical system can only occur if the environment has an energetic population inversion similar to a lasing medium.

Publication Details

Journal
edoc Publication server (Humboldt University of Berlin)
Published
2025-08-30
DOI
https://doi.org/10.18452/34616
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
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article

The Hungry Daemon: Does an Energy-Harvesting Active Particle Have to Obey the Second Law of Thermodynamics?

edoc Publication server (Humboldt University of Berlin)
Advanced Thermodynamics and Statistical Mechanics
article

The Hungry Daemon: Does an Energy-Harvesting Active Particle Have to Obey the Second Law of Thermodynamics?

article en

Abstract

Thought experiments like Maxwell’s Demon or the Smoluchowski–Feynman Ratchet can help in pursuing the microscopic origin of the Second Law of Thermodynamics. Here we present a more sophisticated mechanical system than a ratchet, consisting of a Hamiltonian (non-Brownian) active particle which can harvest energy from an environment which may be in thermal equilibrium at a single temperature. We show that while a phenomenological description would seem to allow the system to operate as a Perpetual Motion Machine of the Second Kind, a full mechanical analysis confirms that this is impossible, and that perpetual energy harvesting within a mechanical system can only occur if the environment has an energetic population inversion similar to a lasing medium.

edoc Publication server (Humboldt University of Berlin)
Openalex Percentile: Top 50%
Advanced Thermodynamics and Statistical Mechanics
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