Research of processes of chemical preposition of nickel as a filler of polymer hydrogels

The kinetic characteristics of the reaction of nickel precipitation by hypophosphites in the volume of the solution were studied, depending on the pH of the medium, temperature, oxidant content, nature and concentration of the activator, and the presence of a water-soluble polymer – polyvinylpyrrolidone (PVP). It was found that the presence of PVP in the solution affects the duration of the induction period and the rate of the reduction reaction, and the nature of the effect of PVP significantly depends on the pH of the medium. It has been proven that the use of previously obtained nickel hydrosols as a reduction activator makes it possible to significantly reduce the duration of the induction period of the reduction reaction at low temperatures.

Publication Details

Journal
Chemistry Technology and Application of Substances
Published
2025-06-01
DOI
https://doi.org/10.23939/ctas2025.01.163
Primary Topic
Geochemistry and Geologic Mapping
Type
article
Field-Weighted Citation Impact
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article

Research of processes of chemical preposition of nickel as a filler of polymer hydrogels

Chemistry Technology and Application of Substances
Geochemistry and Geologic Mapping
article

Research of processes of chemical preposition of nickel as a filler of polymer hydrogels

article en

Abstract

The kinetic characteristics of the reaction of nickel precipitation by hypophosphites in the volume of the solution were studied, depending on the pH of the medium, temperature, oxidant content, nature and concentration of the activator, and the presence of a water-soluble polymer – polyvinylpyrrolidone (PVP). It was found that the presence of PVP in the solution affects the duration of the induction period and the rate of the reduction reaction, and the nature of the effect of PVP significantly depends on the pH of the medium. It has been proven that the use of previously obtained nickel hydrosols as a reduction activator makes it possible to significantly reduce the duration of the induction period of the reduction reaction at low temperatures.

Chemistry Technology and Application of SubstancesVol. 8(1)
Clean water and sanitation
Openalex Percentile: Top 39%
Geochemistry and Geologic Mapping
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