Phase field modelling of the growth and detachment of bubbles in a hydrogen electrolyzer

We develop and implement numerically a phase field model for the growth and detachment of a gas bubble resting on an electrode and being filled with hydrogen produced by water electrolysis. The bubble is surrounded by a viscous liquid, has a prescribed static contact angle and is also subject to gravitational forces. We compute, as a function of the static contact angle, the time at which the bubble detaches from the substrate and what volume it has at that time. We also investigate de dependence of the detachment time on other parameters such as the applied voltage and the hydrogen ion concentration at the fluid bulk.

Publication Details

Journal
ArXiv.org
Published
2025-08-07
Primary Topic
Geochemistry and Geologic Mapping
Type
article
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article

Phase field modelling of the growth and detachment of bubbles in a hydrogen electrolyzer

ArXiv.org
Geochemistry and Geologic Mapping
article

Phase field modelling of the growth and detachment of bubbles in a hydrogen electrolyzer

article en

Abstract

We develop and implement numerically a phase field model for the growth and detachment of a gas bubble resting on an electrode and being filled with hydrogen produced by water electrolysis. The bubble is surrounded by a viscous liquid, has a prescribed static contact angle and is also subject to gravitational forces. We compute, as a function of the static contact angle, the time at which the bubble detaches from the substrate and what volume it has at that time. We also investigate de dependence of the detachment time on other parameters such as the applied voltage and the hydrogen ion concentration at the fluid bulk.

ArXiv.org
Clean water and sanitation
Openalex Percentile: Top 64%
Geochemistry and Geologic Mapping
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Phase field modelling of the growth and detachment of bubbles in a hydrogen electrolyzer · ArXiv.org (2025) | TGRS Research Map | TGRS