Aliovalent metal cation doping of La5Ti2AgO7S5 particles for improved photocatalytic and photoelectrochemical water splitting

The doping of photocatalytic La5Ti2AgO7S5 particles with aliovalent metal cations was investigated. The incorporation of lower-valence Al3+ cations at Ti4+ sites improved the photocatalytic hydrogen evolution activity. In addition, the anodic photocurrent during oxygen evolution was increased upon adding higher-valence Ta5+ ions. The effect of doping on the carrier density in the photocatalytic particles was also examined in this work.