Hydrogen Bond-Controlled Site-Selective C(sp^3)–H Alkylation of Sulfonanilides

We successfully developed a decatungstate-catalyzed benzylic C(sp^3)–H alkylation of sulfonanilides by utilizing the hydrogen bond between the sulfonamide group of the substrates and decatungstate photocatalysts. Using this catalytic system, site-selective C(sp^3)–H alkylation was achieved at the benzylic position near the sulfonamide group.

Publication Details

Journal
Kyushu University Institutional Repository (QIR) (Kyushu University)
Published
2025-02-27
Primary Topic
Subterranean biodiversity and taxonomy
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article
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article

Hydrogen Bond-Controlled Site-Selective C(sp^3)–H Alkylation of Sulfonanilides

Kyushu University Institutional Repository (QIR) (Kyushu University)
Subterranean biodiversity and taxonomy
article

Hydrogen Bond-Controlled Site-Selective C(sp^3)–H Alkylation of Sulfonanilides

article en

Abstract

We successfully developed a decatungstate-catalyzed benzylic C(sp^3)–H alkylation of sulfonanilides by utilizing the hydrogen bond between the sulfonamide group of the substrates and decatungstate photocatalysts. Using this catalytic system, site-selective C(sp^3)–H alkylation was achieved at the benzylic position near the sulfonamide group.

Kyushu University Institutional Repository (QIR) (Kyushu University)
Clean water and sanitation
Openalex Percentile: Top 40%
Subterranean biodiversity and taxonomy
Open Access PDFOpenAlex
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Hydrogen Bond-Controlled Site-Selective C(sp^3)–H Alkylation of Sulfonanilides · Kyushu University Institutional Repository (QIR) (Kyushu University) (2025) | TGRS Research Map | TGRS