Environmental Behaviour of Synthesized and Commercial Agricultural Zinc Products: Leaching, Migration, and Availability in Soils

The aim of this paper is to examine the environmental effect of different chemical characteristics of Zinc (Zn) sources, assessing the transport, leaching and accumulation in the environment in sand, acidic (AS) and calcareous (CS) soils. Comparative short- and long-term studies applying ZnO sources [bulk, laboratory-synthesized and commercial nanoparticles (NP)], ZnSO4, complexed Zn (Zn-lignosulfonate) and chelated Zn (Zn-diethylenetriamine-pentaacetate, Zn-hydroxy-ethylenediamine-tetraacetate and Zn-ethylenediamine-tetraacetate) were carried out. For all treatments and media, the medium- and long-term dissolution kinetic model was fitted to a logistic function. The applied Zn in the form of ZnO was mainly retained at the upper half (0-7.5 cm) of the columns and in very available form (ranging 40-61% of added Zn in AS and 29-31% in CS). Leached Zn reached values below 6% in AS and 3% in CS. The use of chelated Zn in both soils and complexed Zn, and ZnSO4 in AS resulted in excessive leaching of Zn (around 70%). The amount of Zn available at the upper half of the column was less than 5%. In the CS, these fertilizers showed a higher aging than ZnO sources, negatively affecting its availability as a nutrient for crops. ZnO NP showed short- and medium-term dissolution kinetics that allow gradual nutrient release and high availability at the medium-term. These products provide an effective solution for plant nutrition while mitigating the environmental problems observed with more traditional sources related to leaching.