Synthesis of carbazole-based hetero-core-modified porphyrins

Annulation reaction of a 1,1′-(1,3-butadiyne)-8,8′-(2,5-thiophene)-bridged carbazole dimer <bold>10</bold> provided the carbazole-based isophlorines <bold>11a–11c</bold> and <bold>12</bold>. The oxidation of <bold>12</bold> generated the corresponding 21-selena-23-thiaporphyrin <bold>13</bold>.

Publication Details

Journal
Tokyo Tech Research Repository (Tokyo Institute of Technology)
Published
2025-06-28
Primary Topic
Porphyrin and Phthalocyanine Chemistry
Type
article
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article

Synthesis of carbazole-based hetero-core-modified porphyrins

Tokyo Tech Research Repository (Tokyo Institute of Technology)
Porphyrin and Phthalocyanine Chemistry
article

Synthesis of carbazole-based hetero-core-modified porphyrins

article en

Abstract

Annulation reaction of a 1,1′-(1,3-butadiyne)-8,8′-(2,5-thiophene)-bridged carbazole dimer <bold>10</bold> provided the carbazole-based isophlorines <bold>11a–11c</bold> and <bold>12</bold>. The oxidation of <bold>12</bold> generated the corresponding 21-selena-23-thiaporphyrin <bold>13</bold>.

Tokyo Tech Research Repository (Tokyo Institute of Technology)
Openalex Percentile: Top 60%
Porphyrin and Phthalocyanine Chemistry
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Synthesis of carbazole-based hetero-core-modified porphyrins · Tokyo Tech Research Repository (Tokyo Institute of Technology) (2025) | TGRS Research Map | TGRS