Визначення експлуатаційних властивостей гальванічних покриттів на основі кобальту

Abstract. Problem. An effective solution to the problem of the durability of construction materials is the application of protective coatings, which allow tosignificantly expand the scope of use and service life of products. The purpose of the work was to determine the performance characteristics of electrolytic coatings with Co-Ni-Zr alloy, namely adhesion and microhardness. Methodology The microhardness of the coatings was determined by the indentation depth of the diamond pyramid. Coating adhesion was determined by the fracture method. The chemical composition of the obtained coatings was determined by the X-ray fluorescence method using the SPRUT portable spectrometer. The analysis was carried out at least in 3 points with subsequent averaging of the obtained values. Electrodeposition was carried out with a unipolar current in stationary and pulsed modes (ti/tр=2/2) while varying the current density. Originality. There are no signs of delamination of the coatings on the sandpaper, which emphasizes strong adhesion to the base. The results of metallographic studies proved that Co-Ni-Zr coatings have good adhesion to the substrate material and retain it under mechanical loads. The highest value of microhardness – 850.0 MPa was obtained in the galvanostatic mode at i = = 6 A/dm2, while the zirconium content in the alloy is 1.5 wt.%. From the results of the experiments, it can be concluded that the zirconium content does not affect the microhardness of the Co-Ni-Zr coating. When the current density increases, the microhardness of the deposit decreases, which can be explained by reaching the maximum density of the deposition current. The optimal deposition current density for the galvanostatic mode is 6 A/dm2, pulsed 6 A/dm2 for obtaining coatings with high microhardness

Publication Details

Journal
The Scientific Issues of Ternopil Volodymyr Hnatiuk National Pedagogical University Series pedagogy
Published
2024-12-26
Primary Topic
Electrodeposition and Electroless Coatings
Type
article
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article

Визначення експлуатаційних властивостей гальванічних покриттів на основі кобальту

The Scientific Issues of Ternopil Volodymyr Hnatiuk National Pedagogical University Series pedagogy
Electrodeposition and Electroless Coatings
article

Визначення експлуатаційних властивостей гальванічних покриттів на основі кобальту

article en

Abstract

Abstract. Problem. An effective solution to the problem of the durability of construction materials is the application of protective coatings, which allow tosignificantly expand the scope of use and service life of products. The purpose of the work was to determine the performance characteristics of electrolytic coatings with Co-Ni-Zr alloy, namely adhesion and microhardness. Methodology The microhardness of the coatings was determined by the indentation depth of the diamond pyramid. Coating adhesion was determined by the fracture method. The chemical composition of the obtained coatings was determined by the X-ray fluorescence method using the SPRUT portable spectrometer. The analysis was carried out at least in 3 points with subsequent averaging of the obtained values. Electrodeposition was carried out with a unipolar current in stationary and pulsed modes (ti/tр=2/2) while varying the current density. Originality. There are no signs of delamination of the coatings on the sandpaper, which emphasizes strong adhesion to the base. The results of metallographic studies proved that Co-Ni-Zr coatings have good adhesion to the substrate material and retain it under mechanical loads. The highest value of microhardness – 850.0 MPa was obtained in the galvanostatic mode at i = = 6 A/dm2, while the zirconium content in the alloy is 1.5 wt.%. From the results of the experiments, it can be concluded that the zirconium content does not affect the microhardness of the Co-Ni-Zr coating. When the current density increases, the microhardness of the deposit decreases, which can be explained by reaching the maximum density of the deposition current. The optimal deposition current density for the galvanostatic mode is 6 A/dm2, pulsed 6 A/dm2 for obtaining coatings with high microhardness

The Scientific Issues of Ternopil Volodymyr Hnatiuk National Pedagogical University Series pedagogy
Openalex Percentile: Top 64%
Electrodeposition and Electroless Coatings
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