Strengthening the Link Between Fullerenes and a Subset of Diffuse Interstellar Bands

A debate persists regarding the correlation between the DIBs 9577 and 9632 \r{A}, and whether they share a common molecular carrier (i.e., C$_{60}^{+}$). A robust high correlation determination emerges after bridging the baseline across an order of magnitude ($\simeq 50 - 700$ m\r{A}, $r=0.93\pm0.02$), and nearly doubling the important higher equivalent width domain by adding new Mg II-corrected sightlines. Moreover, additional evidence is presented of possible DIB linkages to fullerenes, whereby attention is drawn to DIBs at 7470.38, 7558.44, and 7581.47 \r{A}, which match the Campbell experimental results for C$_{70}^{+}$ within 1 \r{A}, and the same is true of 6926.48 and 7030.26 \r{A} for C$_{70}^{2+}$. Yet their current correlation uncertainties are unsatisfactory and exacerbated by expectedly low EWs (e.g., $\overline{EW}=4$ m\r{A} for 6926.48 \r{A}), and thus further observations are required to assess whether they represent a bona fide connection or numerical coincidence.

Publication Details

Journal
ArXiv.org
Published
2025-03-16
Primary Topic
Fullerene Chemistry and Applications
Type
article
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article

Strengthening the Link Between Fullerenes and a Subset of Diffuse Interstellar Bands

ArXiv.org
Fullerene Chemistry and Applications
article

Strengthening the Link Between Fullerenes and a Subset of Diffuse Interstellar Bands

article en

Abstract

A debate persists regarding the correlation between the DIBs 9577 and 9632 \r{A}, and whether they share a common molecular carrier (i.e., C$_{60}^{+}$). A robust high correlation determination emerges after bridging the baseline across an order of magnitude ($\simeq 50 - 700$ m\r{A}, $r=0.93\pm0.02$), and nearly doubling the important higher equivalent width domain by adding new Mg II-corrected sightlines. Moreover, additional evidence is presented of possible DIB linkages to fullerenes, whereby attention is drawn to DIBs at 7470.38, 7558.44, and 7581.47 \r{A}, which match the Campbell experimental results for C$_{70}^{+}$ within 1 \r{A}, and the same is true of 6926.48 and 7030.26 \r{A} for C$_{70}^{2+}$. Yet their current correlation uncertainties are unsatisfactory and exacerbated by expectedly low EWs (e.g., $\overline{EW}=4$ m\r{A} for 6926.48 \r{A}), and thus further observations are required to assess whether they represent a bona fide connection or numerical coincidence.

ArXiv.org
Openalex Percentile: Top 47%
Fullerene Chemistry and Applications
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