The Three-mm Ultimate Mopra Milky Way Survey. III. Data Release 6, An Atlas of Physical Conditions, Global Mass Conversion Laws, and 3D Physical Architecture of the Molecular ISM in the Fourth Quadrant

We present Data Release 6 of ThrUMMS, consisting of complete data cubes and various moments of line emission ($^{12}$CO, $^{13}$CO, C$^{18}$O) from molecular clouds, across 60$^{\circ}$$\times$2$^{\circ}$ of the Fourth Quadrant (4Q) of the Milky Way at a resolution of 72$''$ in (l,b) and 0.09 kms$^{-1}$ in V$_{LSR}$. From LTE radiative transfer analysis of the data cubes, we compute cubes and moments of the lines' opacity, excitation temperature, and column density $N_{12CO}$. Combining $I_{12CO}$ and $N_{12CO}$ data, we derive a global mass conversion law $N$=$N_{0}I^{p}$, where $N_{0}$$\approx$10$^{18}$mol/m$^{2}$ and $p$=2 at this resolution. We argue that the standard linear $N$=$XI$ is only approximately valid: $p$$\sim$1.5-1.0 at coarser resolutions or in atypical locations, such as Galactic Center clouds. Also, the velocity dispersion distributions are very different between $I_{12CO}$ and $N_{12CO}$, the former preferentially tracing more diffuse molecular gas. We re-evaluated Galactic rotation parameters for the 4Q, defining a new ``BGT'' model, and deprojected the (l,V) data onto (l,d) and (x,y) grids using standard kinematic procedures. To automate distance disambiguation inside the solar circle, we developed a simple $ζ^{+}$ discriminator function and applied it to our deprojections. We discovered two previously unrecognised features of the molecular cloud population: widespread ripples in the midplane of wavelength 4kpc and amplitude 50pc, potentially generated by the last perigalactic passage of the Sgr dwarf; and three distant, massive molecular structures, the Far Ara clouds, two of which exhibit an exceptional velocity gradient, possibly lying in the far end of the Galaxy's Bar or a gas-rich dwarf galaxy $\sim$20-300 kpc beyond the disk