Sedimentation equilibrium as a probe of the pressure equation of state of active colloids

We introduce a theoretical and computational framework for extracting the pressure equation of state (EoS) of an active suspension from its steady-state sedimentation profile. As EoSs are prerequisites for many theories in active matter, determining how pressure depends on key parameters such as density, activity, and interparticle interactions is essential to make quantitative predictions relevant to materials design and engineering applications. Focusing on the one-dimensional active Brownian particle (1D-ABP) model, we show that the pressure measured in a homogeneous periodic system can be recovered from the spatial profiles established in sedimentation equilibrium. Our approach is based on exact mechanical considerations and provides a direct route for determining pressure from experimentally measurable quantities. This work compares sedimentation-derived equations of state with those obtained from periodic simulations, establishing a foundation for using sedimentation as a generic tool to characterize the behavior of active suspensions.

Publication Details

Journal
ArXiv.org
Published
2025-06-20
Primary Topic
Micro and Nano Robotics
Type
article
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article

Sedimentation equilibrium as a probe of the pressure equation of state of active colloids

ArXiv.org
Micro and Nano Robotics
article

Sedimentation equilibrium as a probe of the pressure equation of state of active colloids

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Abstract

We introduce a theoretical and computational framework for extracting the pressure equation of state (EoS) of an active suspension from its steady-state sedimentation profile. As EoSs are prerequisites for many theories in active matter, determining how pressure depends on key parameters such as density, activity, and interparticle interactions is essential to make quantitative predictions relevant to materials design and engineering applications. Focusing on the one-dimensional active Brownian particle (1D-ABP) model, we show that the pressure measured in a homogeneous periodic system can be recovered from the spatial profiles established in sedimentation equilibrium. Our approach is based on exact mechanical considerations and provides a direct route for determining pressure from experimentally measurable quantities. This work compares sedimentation-derived equations of state with those obtained from periodic simulations, establishing a foundation for using sedimentation as a generic tool to characterize the behavior of active suspensions.

ArXiv.org
Openalex Percentile: Top 68%
Micro and Nano Robotics
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