Synthesis and Characterization of Polymer-Metal Chelates Derived from Oxalic Acid and Thiosemicarbazide

Polymeric materials have become increasingly significant due to their wide-ranging applications and adaptability tomodern societal needs. These materials exhibit remarkable properties, including thermal stability, chemical resistance,conductivity, and ion-exchange capacity. The development of polymeric ligands and coordination polymers, particularly thosecontaining donor atoms such as N, S, and O, has expanded their utility in various fields, including catalysis, electronics, surfacecoatings, and biomedical applications. Chelate polymers, formed by coordinating metal ions with organic ligands, exhibit bothorganic and inorganic characteristics, offering desirable magnetic, thermal, and electrical properties. Despite challenges such aspoor solubility and plasticity, chelate polymers are utilized in the aerospace, automotive industries, and semiconductor sectorsdue to their thermal resilience and functional diversity. Recent research has focused on designing low-band-gap conductingpolymers and synthesizing various metal complexes with Schiff bases, hydroxamic acids, and thiosemicarbazones, leading toadvances in coordination chemistry and material science. These developments underline the transformative role of polymers inscience, industry, and everyday life.

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Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2025-07-25
DOI
https://doi.org/10.5281/zenodo.16420177
Primary Topic
Synthesis and properties of polymers
Type
article
Field-Weighted Citation Impact
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article

Synthesis and Characterization of Polymer-Metal Chelates Derived from Oxalic Acid and Thiosemicarbazide

Zenodo (CERN European Organization for Nuclear Research)
Synthesis and properties of polymers
article

Synthesis and Characterization of Polymer-Metal Chelates Derived from Oxalic Acid and Thiosemicarbazide

article en

Abstract

Polymeric materials have become increasingly significant due to their wide-ranging applications and adaptability tomodern societal needs. These materials exhibit remarkable properties, including thermal stability, chemical resistance,conductivity, and ion-exchange capacity. The development of polymeric ligands and coordination polymers, particularly thosecontaining donor atoms such as N, S, and O, has expanded their utility in various fields, including catalysis, electronics, surfacecoatings, and biomedical applications. Chelate polymers, formed by coordinating metal ions with organic ligands, exhibit bothorganic and inorganic characteristics, offering desirable magnetic, thermal, and electrical properties. Despite challenges such aspoor solubility and plasticity, chelate polymers are utilized in the aerospace, automotive industries, and semiconductor sectorsdue to their thermal resilience and functional diversity. Recent research has focused on designing low-band-gap conductingpolymers and synthesizing various metal complexes with Schiff bases, hydroxamic acids, and thiosemicarbazones, leading toadvances in coordination chemistry and material science. These developments underline the transformative role of polymers inscience, industry, and everyday life.

Zenodo (CERN European Organization for Nuclear Research)
Nagpur Institute of Technology (IN)
Industry, innovation and infrastructure
Openalex Percentile: Top 58%
Synthesis and properties of polymers
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