Isotherm and Thermodynamic Investigation on Removal of Pb(II) from Aqueous Solutions by Graphene Oxide and Magnetic Graphene Oxide: A Comparative Study

One of the most effective approaches for removing heavy metal ions from an aqueous solution is adsorption. However, the synthesis of adsorbents with intended selectivity and performance is a major obstacle in the fight against water pollution. The objective of this investigation is to address the constraints of Graphene Oxide (GO) as an adsorbent by synthesizing Magnetic Graphene Oxide (MGO). Both GO and MGO were synthesized, and their adsorption capacity for heavy metal ions such as lead (Pb (II)) was investigated. The maximum adsorption capacities (Qmax) of GO and MGO under optimal conditions (pH = 6, temperature = 50℃, and contact time = 20 minutes) were determined to be 46.19 mg/g and 49.8 mg/g, respectively. This indicates that magnetizing graphene oxide with iron oxide nanoparticles not only addresses its separation challenges but also enhances its adsorption capacity. Thermodynamic analyses indicated that the adsorption process was spontaneous and endothermic.

Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2025-04-02
DOI
https://doi.org/10.5281/zenodo.15125582
Primary Topic
Adsorption and biosorption for pollutant removal
Type
article
Field-Weighted Citation Impact
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article

Isotherm and Thermodynamic Investigation on Removal of Pb(II) from Aqueous Solutions by Graphene Oxide and Magnetic Graphene Oxide: A Comparative Study

Zenodo (CERN European Organization for Nuclear Research)
Adsorption and biosorption for pollutant removal
article

Isotherm and Thermodynamic Investigation on Removal of Pb(II) from Aqueous Solutions by Graphene Oxide and Magnetic Graphene Oxide: A Comparative Study

article en

Abstract

One of the most effective approaches for removing heavy metal ions from an aqueous solution is adsorption. However, the synthesis of adsorbents with intended selectivity and performance is a major obstacle in the fight against water pollution. The objective of this investigation is to address the constraints of Graphene Oxide (GO) as an adsorbent by synthesizing Magnetic Graphene Oxide (MGO). Both GO and MGO were synthesized, and their adsorption capacity for heavy metal ions such as lead (Pb (II)) was investigated. The maximum adsorption capacities (Qmax) of GO and MGO under optimal conditions (pH = 6, temperature = 50℃, and contact time = 20 minutes) were determined to be 46.19 mg/g and 49.8 mg/g, respectively. This indicates that magnetizing graphene oxide with iron oxide nanoparticles not only addresses its separation challenges but also enhances its adsorption capacity. Thermodynamic analyses indicated that the adsorption process was spontaneous and endothermic.

Zenodo (CERN European Organization for Nuclear Research)
Clean water and sanitation
Openalex Percentile: Top 57%
Adsorption and biosorption for pollutant removal
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Isotherm and Thermodynamic Investigation on Removal of Pb(II) from Aqueous Solutions by Graphene Oxide and Magnetic Graphene Oxide: A Comparative Study · Zenodo (CERN European Organization for Nuclear Research) (2025) | TGRS Research Map | TGRS