π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene
We report hitherto elusive side‐on η2‐bonded palladium(0) carbonyl (anthraquinone, benzaldehyde) and arene (benzene, hexafluorobenzene) palladium(0) complexes and present the catalytic hydrodefluorination of hexafluorobenzene by cyclohexene. The comparison with respective cyclohexene, pyridine and tetrahydrofuran complexes reveals that the experimental ligand binding strengths follow the order THF
Publication Details
- Journal
- edoc Publication server (Humboldt University of Berlin)
- Published
- 2024-12-23
- DOI
- https://doi.org/10.18452/33297
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00