π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene

We report hitherto elusive side‐on η2‐bonded palladium(0) carbonyl (anthraquinone, benzaldehyde) and arene (benzene, hexafluorobenzene) palladium(0) complexes and present the catalytic hydrodefluorination of hexafluorobenzene by cyclohexene. The comparison with respective cyclohexene, pyridine and tetrahydrofuran complexes reveals that the experimental ligand binding strengths follow the order THF

Publication Details

Journal
Refubium (Universitätsbibliothek der Freien Universität Berlin)
Published
2025-01-01
DOI
https://doi.org/10.17169/refubium-47292
Primary Topic
Organometallic Complex Synthesis and Catalysis
Type
article
Field-Weighted Citation Impact
0.00

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article

π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene

Refubium (Universitätsbibliothek der Freien Universität Berlin)
Organometallic Complex Synthesis and Catalysis
article

π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene

article en

Abstract

We report hitherto elusive side‐on η2‐bonded palladium(0) carbonyl (anthraquinone, benzaldehyde) and arene (benzene, hexafluorobenzene) palladium(0) complexes and present the catalytic hydrodefluorination of hexafluorobenzene by cyclohexene. The comparison with respective cyclohexene, pyridine and tetrahydrofuran complexes reveals that the experimental ligand binding strengths follow the order THF

Refubium (Universitätsbibliothek der Freien Universität Berlin)
European Commission, Universität des Saarlandes
Openalex Percentile: Top 51%
Organometallic Complex Synthesis and Catalysis
DOIOpen Access PDFOpenAlex
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π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene · Refubium (Universitätsbibliothek der Freien Universität Berlin) (2025) | TGRS Research Map | TGRS