Simultaneous NO\nand CO Removal through Bimetallic\nRedox Pairs Composed of Mesoporous Indium Oxide

Designing new catalytic materials with bi- or trimetallic\ncores\nfor higher catalytic performance is a key aspect of current research.\nThe current research describes the effect of an indium-based composite\ncatalyst, synthesized through the glycine combustion route, for the\nconversion of toxic CO and NO into nontoxic ones. Among the prepared\nmaterials, the cobalt–copper-composed indium oxide catalyst\nexhibited the highest performance in detoxifying CO and NO. The notable\nimprovement in the redox nature of the mesoporous catalyst displayed\nthe CO–O<sub>2</sub> conversion at 160 °C and NO–CO\nconversion at 220 °C, respectively. The insertion of Co along\nwith Cu tends to enhance the redox pair as attributed to the synergistic\ninterplay among Co<sup>2+/3+</sup>–Cu<sup>1+/2+</sup>, as evidenced\nthrough the TPR profile. The presented trimetallic core of indium,\ncopper, and cobalt facilitates high surface properties, highlighting\nthe importance of precise effectiveness in catalyst design in NO and\nCO conversion.

Publication Details

Journal
Figshare
Published
2024-12-09
DOI
https://doi.org/10.1021/acs.jpcc.4c03944.s001
Primary Topic
Wheat and Barley Genetics and Pathology
Type
article
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article

Simultaneous NO\nand CO Removal through Bimetallic\nRedox Pairs Composed of Mesoporous Indium Oxide

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Wheat and Barley Genetics and Pathology
article

Simultaneous NO\nand CO Removal through Bimetallic\nRedox Pairs Composed of Mesoporous Indium Oxide

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Abstract

Designing new catalytic materials with bi- or trimetallic\ncores\nfor higher catalytic performance is a key aspect of current research.\nThe current research describes the effect of an indium-based composite\ncatalyst, synthesized through the glycine combustion route, for the\nconversion of toxic CO and NO into nontoxic ones. Among the prepared\nmaterials, the cobalt–copper-composed indium oxide catalyst\nexhibited the highest performance in detoxifying CO and NO. The notable\nimprovement in the redox nature of the mesoporous catalyst displayed\nthe CO–O<sub>2</sub> conversion at 160 °C and NO–CO\nconversion at 220 °C, respectively. The insertion of Co along\nwith Cu tends to enhance the redox pair as attributed to the synergistic\ninterplay among Co<sup>2+/3+</sup>–Cu<sup>1+/2+</sup>, as evidenced\nthrough the TPR profile. The presented trimetallic core of indium,\ncopper, and cobalt facilitates high surface properties, highlighting\nthe importance of precise effectiveness in catalyst design in NO and\nCO conversion.

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Openalex Percentile: Top 38%
Wheat and Barley Genetics and Pathology
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