Kilonova ejecta opacity inferred from new large-scale HFR atomic calculations in all elements between Ca (

Context. The production of elements heavier than iron in the Universe still remains an unsolved mystery. About half of them are thought to be produced by the astrophysical r-process (rapid neutron-capture process), for which neutron star mergers (NSMs) are among the most promising production sites. In August 2017, gravitational waves generated by a NSM were detected for the first time by the LIGO detectors (event GW170817), and the observation of its electromagnetic counterpart, the kilonova (KN) AT2017gfo, suggested the presence of heavy elements in the KN ejecta. The luminosity and spectra of such KN emission depend significantly on the ejecta opacity. Atomic data and opacities for heavy elements are thus sorely needed to model and interpret KN light curves and spectra. Aims. The present work focuses on large-scale atomic data and opacity computations for all heavy elements with Z ≥ 20, with a special effort on lanthanides and actinides, for a grid of typical KN ejecta conditions (temperature, density, and time post-merger) between one day and one week after the merger (corresponding to the local thermodynamical equilibrium photosphere phase of the KN ejecta). Methods. In order to do so, we used the pseudo-relativistic Hartree–Fock (HFR) method as implemented in Cowan’s codes, in which the choice of the interaction configuration model is of crucial importance. Results. In this paper, HFR atomic data and opacities for all elements between Ca (Z = 20) and Lr (Z = 103) are presented, with a special focus on lanthanides and actinides. In particular, we found increased lanthanide opacities compared to previous works. Besides, we also discuss the contribution of every single element with Z ≥ 20 to the total KN ejecta opacity for a given NSM model, depending on their Planck mean opacities and elemental abundances. An important result is that lanthanides are found to not be the dominant sources of opacity, at least on average. The impact on KN light curves of considering such atomic-physics-based opacity data instead of typical crude approximation formulae is also evaluated. In addition, the importance of taking the ejecta composition into account directly in the expansion opacity determination (instead of estimating single-element opacities) is highlighted. A database containing all the relevant atomic data and opacity tables has also been created and published online along with this work.