Cobalt-Catalyzed\nRegioselective C8–H Sulfoxamination\nof 1‑Naphthylamine Derivatives with NH-Sulfoximines

A simple cobalt-catalyzed,\npicolinamide-directed C8–H sulfoxamination\nof 1-naphthalamides with NH-sulfoximines has been developed. This\ncross-dehydrogenative C–H/N–H coupling reaction offers\na facile route to N-arylated sulfoximines, exhibiting high yields,\na broad substrate scope, and excellent functional group tolerance\nand scalability.

Publication Details

Journal
Figshare
Published
2024-11-18
DOI
https://doi.org/10.1021/acs.joc.4c02318.s001
Primary Topic
Enzyme Structure and Function
Type
article
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article

Cobalt-Catalyzed\nRegioselective C8–H Sulfoxamination\nof 1‑Naphthylamine Derivatives with NH-Sulfoximines

Figshare
Enzyme Structure and Function
article

Cobalt-Catalyzed\nRegioselective C8–H Sulfoxamination\nof 1‑Naphthylamine Derivatives with NH-Sulfoximines

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Abstract

A simple cobalt-catalyzed,\npicolinamide-directed C8–H sulfoxamination\nof 1-naphthalamides with NH-sulfoximines has been developed. This\ncross-dehydrogenative C–H/N–H coupling reaction offers\na facile route to N-arylated sulfoximines, exhibiting high yields,\na broad substrate scope, and excellent functional group tolerance\nand scalability.

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Enzyme Structure and Function
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Cobalt-Catalyzed\nRegioselective C8–H Sulfoxamination\nof 1‑Naphthylamine Derivatives with NH-Sulfoximines · Figshare (2024) | TGRS Research Map | TGRS