Switchable Synthesis\nof Tritylone Alcohols and 2‑Benzoylbenzoate\nEsters from Spiroindane-1,3-diones

A solvent-controlled regioselective rearrangement reaction\nof spiroindane-1,3-diones\nwith a leaving group has been developed. In acetonitrile solvent,\nthe spiroindane-1,3-diones <b>3</b> were rearranged to provide\ntritylone alcohols, while 2-benzoylbenzoate ester derivatives were\nobtained if the reactions were performed in alcohols.

Publication Details

Journal
Figshare
Published
2024-08-12
DOI
https://doi.org/10.1021/acs.joc.4c01296.s001
Primary Topic
Plant Pathogens and Resistance
Type
article
Field-Weighted Citation Impact
0.00
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article

Switchable Synthesis\nof Tritylone Alcohols and 2‑Benzoylbenzoate\nEsters from Spiroindane-1,3-diones

Figshare
Plant Pathogens and Resistance
article

Switchable Synthesis\nof Tritylone Alcohols and 2‑Benzoylbenzoate\nEsters from Spiroindane-1,3-diones

article en

Abstract

A solvent-controlled regioselective rearrangement reaction\nof spiroindane-1,3-diones\nwith a leaving group has been developed. In acetonitrile solvent,\nthe spiroindane-1,3-diones <b>3</b> were rearranged to provide\ntritylone alcohols, while 2-benzoylbenzoate ester derivatives were\nobtained if the reactions were performed in alcohols.

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Plant Pathogens and Resistance
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