Preparation of ZnO/Co/C/RGO\nComposites for Enhanced\nMicrowave Absorption

ZnO/Co/C/reduced\ngraphene oxide (RGO) composites are synthesized\nthrough carbonization of ZnCo-MOF-5/GO under an Ar/H<sub>2</sub> flow.\nThe abundant active sites (e.g., functional groups and lattice defects),\ncopious heterointerfaces (among Co, ZnO, C, and RGO), and wrinkled\narchitecture trigger multiple dipole polarization, interface polarization,\nand enhanced conductive loss. By adjusting the content of RGO, the\nelectromagnetic parameters for ZnO/Co/C/RGO composites were effectively\nregulated. The minimum reflection loss (RL<sub>min</sub>) of ZnO/Co/C/RGO-50\ncomposites is −52.72 dB at 1.70 mm, and the EAB is 3.57 GHz.\nFuthermore, CST simulation results further confirm the remarkable\nRCS reduction capacity for ZnO/Co/C/RGO-50 composites. The reduction\nvalue of RCS is 22.84 dB m<sup>2</sup>, and effective absorption can\nreach the entire angle range. The superior microwave absorption property\nfor ZnO/Co/C/RGO composites is benefited from cooperative action of\ndielectric loss (dipole polarization, interface polarization, conductive\nloss) and magnetic loss (natural resonance and exchange resonance).

Publication Details

Journal
Figshare
Published
2024-12-10
DOI
https://doi.org/10.1021/acsanm.4c05369.s001
Primary Topic
Electromagnetic wave absorption materials
Type
article
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article

Preparation of ZnO/Co/C/RGO\nComposites for Enhanced\nMicrowave Absorption

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Electromagnetic wave absorption materials
article

Preparation of ZnO/Co/C/RGO\nComposites for Enhanced\nMicrowave Absorption

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Abstract

ZnO/Co/C/reduced\ngraphene oxide (RGO) composites are synthesized\nthrough carbonization of ZnCo-MOF-5/GO under an Ar/H<sub>2</sub> flow.\nThe abundant active sites (e.g., functional groups and lattice defects),\ncopious heterointerfaces (among Co, ZnO, C, and RGO), and wrinkled\narchitecture trigger multiple dipole polarization, interface polarization,\nand enhanced conductive loss. By adjusting the content of RGO, the\nelectromagnetic parameters for ZnO/Co/C/RGO composites were effectively\nregulated. The minimum reflection loss (RL<sub>min</sub>) of ZnO/Co/C/RGO-50\ncomposites is −52.72 dB at 1.70 mm, and the EAB is 3.57 GHz.\nFuthermore, CST simulation results further confirm the remarkable\nRCS reduction capacity for ZnO/Co/C/RGO-50 composites. The reduction\nvalue of RCS is 22.84 dB m<sup>2</sup>, and effective absorption can\nreach the entire angle range. The superior microwave absorption property\nfor ZnO/Co/C/RGO composites is benefited from cooperative action of\ndielectric loss (dipole polarization, interface polarization, conductive\nloss) and magnetic loss (natural resonance and exchange resonance).

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Electromagnetic wave absorption materials
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