Defunctionalization Enabled by Intramolecular Radical\nAromatic <i>Ipso</i> Substitution

A chemoselective\nand regioselective copper-promoted defunctionalization\nprocedure has been developed, enabling the rapid construction of various <i>N</i>-polyheterocycles. Initial mechanistic studies reveal that\na single-electron transfer radical process is potentially involved.

Publication Details

Journal
Figshare
Published
2024-09-05
DOI
https://doi.org/10.1021/acs.orglett.4c02910.s001
Primary Topic
Ego Development and Educational Practices
Type
article
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article

Defunctionalization Enabled by Intramolecular Radical\nAromatic Ipso Substitution

Figshare
Ego Development and Educational Practices
article

Defunctionalization Enabled by Intramolecular Radical\nAromatic Ipso Substitution

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Abstract

A chemoselective\nand regioselective copper-promoted defunctionalization\nprocedure has been developed, enabling the rapid construction of various <i>N</i>-polyheterocycles. Initial mechanistic studies reveal that\na single-electron transfer radical process is potentially involved.

Figshare
Industry, innovation and infrastructure
Openalex Percentile: Top 45%
Ego Development and Educational Practices
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Defunctionalization Enabled by Intramolecular Radical\nAromatic <i>Ipso</i> Substitution · Figshare (2024) | TGRS Research Map | TGRS