Dual-Functional Heterogeneous Rh–Sb Alloy NanomaterialsCoupling Electrochemical Hydrazine Oxidation and Hydrogen Evolution

The overall hydrazine splitting (OHzS, N₂H₄ → N₂ + 2H₂) reaction, which is integrated by electrocatalytic hydrazine oxidation reaction (HzOR) and hydrogen evolution reaction (HER), provides an energy-efficient alternative to conventional overall water splitting (OWS) for sustainable hydrogen production. Herein, we present the controlled synthesis of Rh₁Sb₁@Rh–Sb nanoflowers (NFs) that comprise intermetallic Rh₁Sb₁ nanodendrite cores and ultrathin Rh–Sb random alloy nanosheet shells. The alloying of Sb enhances both HzOR and HER performances of Rh nanocatalysts through modulation of growth mechanisms, morphological evolution, and surface electronic configurations. Remarkably, a symmetrical OHzS electrolyzer employing Rh₁Sb₁@Rh–Sb NFs as bifunctional catalysts for both electrodes achieves the current densities of 100 and 500 mA cm^–2 at cell voltages of merely 0.216 and 0.700 V (without <i>iR</i> compensation), respectively, corresponding to 88.1% and 71.9% reductions in electricity consumption compared to alkaline OWS systems. Furthermore, a rechargeable zinc–hydrazine (Zn–Hz) battery using Rh₁Sb₁@Rh–Sb NFs as the positive electrode exhibits high energy efficiency, power density, and durability. The prototype device, integrating a photovoltaic cell, a Zn–Hz battery, and an OHzS cell, demonstrates the potential for efficient and simultaneous solar energy storage, hydrazine pollutant remediation, and hydrogen generation, offering a promising avenue for practical applications.