Synthesis, Characterization, and Evaluation of Anion Removal Properties of Cationic Derivatives of Waste Triglycerides

Waste cooking oils (WCO) exert a detrimental effect on the environment. It is crucial for our future to either reuse or eliminate those materials. This study assesses the cationic derivatives of triglycerides derived from plant oils. Furthermore, the research also examines the potential of the synthesized materials to remove anions. The process of creating cationic derivatives involves three distinct phases. The initial procedure involves the epoxidation of the utilized cooking oil (WCO). The next procedure involves the amalgamation of epoxidized waste cooking oil (EWO) with monochloroacetic acid (MCA). The last stage involves the quaternarization reaction using tertiary amines. Triethylamine and pyridine were employed for the process of quaternarization. The derivatives were investigated using FTIR and 1H NMR spectroscopy techniques. It was determined that each altered triglyceride contains three quaternary amine groups. Insoluble adducts are generated when these chemicals are combined with multivalent anions. One gram of QT-EWO-MCA can absorb 0.059 g of carbonate, 0.0947 g of sulfate, and 0.0947 g of monohydrogen phosphate.

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Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2024-12-09
DOI
https://doi.org/10.5281/zenodo.14327108
Primary Topic
Historical Studies on Reproduction, Gender, Health, and Societal Changes
Type
article
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article

Synthesis, Characterization, and Evaluation of Anion Removal Properties of Cationic Derivatives of Waste Triglycerides

Zenodo (CERN European Organization for Nuclear Research)
Historical Studies on Reproduction, Gender, Health, and Societal Changes
article

Synthesis, Characterization, and Evaluation of Anion Removal Properties of Cationic Derivatives of Waste Triglycerides

article en

Abstract

Waste cooking oils (WCO) exert a detrimental effect on the environment. It is crucial for our future to either reuse or eliminate those materials. This study assesses the cationic derivatives of triglycerides derived from plant oils. Furthermore, the research also examines the potential of the synthesized materials to remove anions. The process of creating cationic derivatives involves three distinct phases. The initial procedure involves the epoxidation of the utilized cooking oil (WCO). The next procedure involves the amalgamation of epoxidized waste cooking oil (EWO) with monochloroacetic acid (MCA). The last stage involves the quaternarization reaction using tertiary amines. Triethylamine and pyridine were employed for the process of quaternarization. The derivatives were investigated using FTIR and 1H NMR spectroscopy techniques. It was determined that each altered triglyceride contains three quaternary amine groups. Insoluble adducts are generated when these chemicals are combined with multivalent anions. One gram of QT-EWO-MCA can absorb 0.059 g of carbonate, 0.0947 g of sulfate, and 0.0947 g of monohydrogen phosphate.

Zenodo (CERN European Organization for Nuclear Research)
Istanbul University-Cerrahpaşa (TR), Istanbul University (TR)
Openalex Percentile: Top 39%
Historical Studies on Reproduction, Gender, Health, and Societal Changes
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