USE OF SODIUM RHODIZONATE IN FIREARM USE CASES: CAN IT BE USEFUL IN IDENTIFYING THE SHOOTER?

The sodium rhodizonate test is a simple colorimetric technique used to identify traces of lead and barium. A positive test provides rapid and photographically documentable results for shots fired at distances not exceeding 50 cm. Usually, this method is not used for identification of the firing hand, which is detected by electron microscopy with energy dispersive analysis (SEM-EDX), requiring the removal of any particles on the surface to be analyzed by STUB. The use of Sodium Rhodizonate, which is undoubtedly less selective, has the disadvantage of target element solubilization (lead and barium) and thus the loss of the preliminary morphological investigation of the particles. The purpose of this paper is to demonstrate that the two indicated methods can be considered complementary in the following order: 1. buffer sampling for electron microscopy investigation (STUB); 2. and subsequent performance of the Sodium Rhodizonate Test. In some special cases, when it is necessary to obtain the result more quickly, with regards to respecting the chronology of the aforementioned tests, it may be useful to carry out the Sodium Rhodizonate Test first, especially when particular and perhaps antiquated weapons were used for suicidal purposes causing considerable gas dispersion and shot residues from the mechanisms. This research illustrates how significant results were obtained substantiating the suicide hypothesis, following the use of an old revolver (year of manufacture around 1915-1920).