Visible-Light-Induced Radical Hydroaroylation of VinylBoronic Ester with Aroyl Chlorides to Access β‑BorylKetones

A visible-light-induced radical hydroaroylation of vinyl boronic ester with aroyl chlorides has been developed, yielding a variety of β-boryl ketones in moderate to good yields with broad functional group tolerance. This metal-free transformation offers a convenient and practical route to access valuable β-boryl ketones from readily available aroyl chlorides and vinyl boronic ester.

Publication Details

Journal
Figshare
Published
2025-03-27
DOI
https://doi.org/10.1021/acs.orglett.5c00996.s001
Primary Topic
Mycorrhizal Fungi and Plant Interactions
Type
article
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article

Visible-Light-Induced Radical Hydroaroylation of VinylBoronic Ester with Aroyl Chlorides to Access β‑BorylKetones

Figshare
Mycorrhizal Fungi and Plant Interactions
article

Visible-Light-Induced Radical Hydroaroylation of VinylBoronic Ester with Aroyl Chlorides to Access β‑BorylKetones

article en

Abstract

A visible-light-induced radical hydroaroylation of vinyl boronic ester with aroyl chlorides has been developed, yielding a variety of β-boryl ketones in moderate to good yields with broad functional group tolerance. This metal-free transformation offers a convenient and practical route to access valuable β-boryl ketones from readily available aroyl chlorides and vinyl boronic ester.

Figshare
Openalex Percentile: Top 53%
Mycorrhizal Fungi and Plant Interactions
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Visible-Light-Induced Radical Hydroaroylation of VinylBoronic Ester with Aroyl Chlorides to Access β‑BorylKetones · Figshare (2025) | TGRS Research Map | TGRS