Ultrafast Binder-FreeCorona Discharge-Enabled AutomatedElectrostatic Patterning (AEP) Technique

Patterning techniques have garnered extensive attention within the realm of printed electronics owing to their substantial contributions across multifarious applications. A plethora of printing methodologies have emerged to generate intricate 2D patterns, each designed to achieve distinct functionalities. However, most prevailing printing techniques necessitate the utilization of binders, meticulous formulation of ink, compatibility checks with printing nozzles, and rigorous cleaning processes when direct contact methods are employed, all of which consume significant time. This paper introduces an ultrafast binder-free method termed corona discharge-enabled automated electrostatic patterning (AEP), capable of printing sub-100 μm resolution patterns within a mere 2 s time frame. A comprehensive investigation into the mechanism underlying AEP is presented, elucidating its printing principles via theoretical derivations, COMSOL simulations, and high-speed camera observation. The manufacturing of high-quality flexible electronics has also been demonstrated. Because of the autopatterning and binder-free nature of AEP, it can significantly improve the manufacturing efficiency of printed electronics with the advantages of high sensitivity and elimination of the ink drying process and mask abrasion.