Photoinduced,\nRedox-Neutral Decyanative and Defluorinative\nPhosphination of (Hetero)Arenes

Triarylphosphines play a crucial role in organic synthesis\nas versatile\ncomponents serving as ligands, catalysts, and reactants. This study\nintroduces a metal-free, visible-light-induced method for the cross-coupling\nof cyanopyridines or polyfluoroarenes with diarylphosphines. This\napproach facilitates the formation of C(sp<sup>2</sup>)–P bonds\nthrough redox-neutral decyanative or defluorinative process, enabling\nthe convenient synthesis of diverse triarylphosphines.

Publication Details

Journal
Figshare
Published
2024-09-16
DOI
https://doi.org/10.1021/acs.orglett.4c03049.s001
Primary Topic
Mycorrhizal Fungi and Plant Interactions
Type
article
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article

Photoinduced,\nRedox-Neutral Decyanative and Defluorinative\nPhosphination of (Hetero)Arenes

Figshare
Mycorrhizal Fungi and Plant Interactions
article

Photoinduced,\nRedox-Neutral Decyanative and Defluorinative\nPhosphination of (Hetero)Arenes

article en

Abstract

Triarylphosphines play a crucial role in organic synthesis\nas versatile\ncomponents serving as ligands, catalysts, and reactants. This study\nintroduces a metal-free, visible-light-induced method for the cross-coupling\nof cyanopyridines or polyfluoroarenes with diarylphosphines. This\napproach facilitates the formation of C(sp<sup>2</sup>)–P bonds\nthrough redox-neutral decyanative or defluorinative process, enabling\nthe convenient synthesis of diverse triarylphosphines.

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Mycorrhizal Fungi and Plant Interactions
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Photoinduced,\nRedox-Neutral Decyanative and Defluorinative\nPhosphination of (Hetero)Arenes · Figshare (2024) | TGRS Research Map | TGRS