Electrooxidative\n1,3-Oxo/Carboamination of Arylcyclopropanes

Herein, the work demonstrates an electrochemically paired\nelectrolysis\napproach facilitating the efficient achievement of the electrooxidative\n1,3-oxo/carboamination of arylcyclopropanes under mild conditions.\nThe formation of 1,3-arylamination of arylcyclopropanes involves commercially\navailable amine redox mediators through a radical–radical process.\nIn addition, the successful execution of β-amino ketones also\noccurs under atmospheric conditions. The control experiments supported\nthe existence of key benzylic radical intermediates in the reaction\npathway.