Photocatalytic α‑C(sp<sup>3</sup>)–HArylation/Heteroarylation of Amines Enabled by Pyrylium Salt

A general photocatalytic α-C­(sp<sup>3</sup>)–H arylation/heteroarylation of amines has been developed. In the presence of the newly designed DPA-TPT, the reaction can operate under mild conditions and produce a diverse array of tertiary benzylic amines in good yields. Additionally, the late-stage arylation of tetracaine demonstrated the practical application of this protocol, highlighting its versatility and efficiency in functionalizing complex molecules.

Publication Details

Journal
Figshare
Published
2025-03-06
DOI
https://doi.org/10.1021/acs.joc.5c00090.s001
Primary Topic
Mycorrhizal Fungi and Plant Interactions
Type
article
Field-Weighted Citation Impact
0.00
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Photocatalytic α‑C(sp3)–HArylation/Heteroarylation of Amines Enabled by Pyrylium Salt

Figshare
Mycorrhizal Fungi and Plant Interactions
article

Photocatalytic α‑C(sp3)–HArylation/Heteroarylation of Amines Enabled by Pyrylium Salt

article en

Abstract

A general photocatalytic α-C­(sp<sup>3</sup>)–H arylation/heteroarylation of amines has been developed. In the presence of the newly designed DPA-TPT, the reaction can operate under mild conditions and produce a diverse array of tertiary benzylic amines in good yields. Additionally, the late-stage arylation of tetracaine demonstrated the practical application of this protocol, highlighting its versatility and efficiency in functionalizing complex molecules.

Figshare
Openalex Percentile: Top 54%
Mycorrhizal Fungi and Plant Interactions
DOISourceOpenAlex
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Photocatalytic α‑C(sp<sup>3</sup>)–HArylation/Heteroarylation of Amines Enabled by Pyrylium Salt · Figshare (2025) | TGRS Research Map | TGRS