Co-Pyrolysis ofBanana Pseudostem and Plastic Wasteby Thermogravimetry: Kinetics and Modeling with Artificial NeuralNetworks

This study investigates the synergy and performance of copyrolysis between banana pseudostem (BPS) and plastic residuespolyethylene terephthalate (PET) and polypropylene (PP)using thermogravimetric analysis and artificial neural network (ANN) modeling. Results indicated that all parameters characterizing copyrolysis increased with plastic proportion in the mixture (initial temperature, maximum weight loss rate, and final residual mass). Optimal synergy was achieved at 30 K/min for 25% PET/75% BPS blend, yielding the lowest activation energy (139.7 kJ/mol), and at 10 K/min for the 50% PP/50% BPS blend (133.1 kJ/mol). The ANN model demonstrated high predictive accuracy (<i>R</i><sup>2</sup> above 0.999), with predicted and experimental weight loss data closely aligned with those obtained experimentally, and activation energy results showed less than 5% relative error from experimental data in most cases. These findings underscore ANN’s reliability in generalizing weight loss data and activation energy predictions across various conditions, offering a novel and efficient approach to optimizing pyrolysis processes compared to traditional methods.

Publication Details

Journal
Figshare
Published
2025-03-14
DOI
https://doi.org/10.1021/acs.iecr.4c04723.s001
Primary Topic
Mycorrhizal Fungi and Plant Interactions
Type
article
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article

Co-Pyrolysis ofBanana Pseudostem and Plastic Wasteby Thermogravimetry: Kinetics and Modeling with Artificial NeuralNetworks

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Mycorrhizal Fungi and Plant Interactions
article

Co-Pyrolysis ofBanana Pseudostem and Plastic Wasteby Thermogravimetry: Kinetics and Modeling with Artificial NeuralNetworks

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Abstract

This study investigates the synergy and performance of copyrolysis between banana pseudostem (BPS) and plastic residuespolyethylene terephthalate (PET) and polypropylene (PP)using thermogravimetric analysis and artificial neural network (ANN) modeling. Results indicated that all parameters characterizing copyrolysis increased with plastic proportion in the mixture (initial temperature, maximum weight loss rate, and final residual mass). Optimal synergy was achieved at 30 K/min for 25% PET/75% BPS blend, yielding the lowest activation energy (139.7 kJ/mol), and at 10 K/min for the 50% PP/50% BPS blend (133.1 kJ/mol). The ANN model demonstrated high predictive accuracy (<i>R</i><sup>2</sup> above 0.999), with predicted and experimental weight loss data closely aligned with those obtained experimentally, and activation energy results showed less than 5% relative error from experimental data in most cases. These findings underscore ANN’s reliability in generalizing weight loss data and activation energy predictions across various conditions, offering a novel and efficient approach to optimizing pyrolysis processes compared to traditional methods.

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Co-Pyrolysis ofBanana Pseudostem and Plastic Wasteby Thermogravimetry: Kinetics and Modeling with Artificial NeuralNetworks · Figshare (2025) | TGRS Research Map | TGRS