Cyclocondensation of Aniline, Dimedone, and NinhydrinUsing Zirconium-Schiff Base Anchored to Silica-Coated with CopperFerrite as a Novel Nanocatalyst Under Benign Condition

This study seeks to demonstrate an environmentally friendly approach to synthesizing indenoindolone compounds. Ninhydrin, aniline, and dimedone were combined in a single step using water and ethanol as solvents, offering more environmentally friendly methods. Copper ferrite nanoparticles were used to help with the reaction as a catalyst. Zirconium chloride was stabilized on a Schiff base and placed on the surface of silica-covered copper ferrite magnetic nanoparticles. This was made and used as a reusable acid catalyst to obtain a high yield of product quickly. The structure of the nanocatalyst was checked using several methods such as FT-IR, ATR, XRD, FE-SEM, EDX, VSM, and TGA. The structure of the organic products was looked at by measuring their melting point and using FT-IR, <sup>1</sup>H NMR, and <sup>13</sup>C NMR tests.

Publication Details

Journal
Figshare
Published
2025-03-28
DOI
https://doi.org/10.1021/acsomega.5c00325.s001
Primary Topic
Mycorrhizal Fungi and Plant Interactions
Type
article
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article

Cyclocondensation of Aniline, Dimedone, and NinhydrinUsing Zirconium-Schiff Base Anchored to Silica-Coated with CopperFerrite as a Novel Nanocatalyst Under Benign Condition

Figshare
Mycorrhizal Fungi and Plant Interactions
article

Cyclocondensation of Aniline, Dimedone, and NinhydrinUsing Zirconium-Schiff Base Anchored to Silica-Coated with CopperFerrite as a Novel Nanocatalyst Under Benign Condition

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Abstract

This study seeks to demonstrate an environmentally friendly approach to synthesizing indenoindolone compounds. Ninhydrin, aniline, and dimedone were combined in a single step using water and ethanol as solvents, offering more environmentally friendly methods. Copper ferrite nanoparticles were used to help with the reaction as a catalyst. Zirconium chloride was stabilized on a Schiff base and placed on the surface of silica-covered copper ferrite magnetic nanoparticles. This was made and used as a reusable acid catalyst to obtain a high yield of product quickly. The structure of the nanocatalyst was checked using several methods such as FT-IR, ATR, XRD, FE-SEM, EDX, VSM, and TGA. The structure of the organic products was looked at by measuring their melting point and using FT-IR, <sup>1</sup>H NMR, and <sup>13</sup>C NMR tests.

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Mycorrhizal Fungi and Plant Interactions
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