Auto-Tandem Catalyst: From Allylic Alcohols to SecondaryAlcohols via Redox Isomerization/Atmospheric Hydrogenation in WaterCatalyzed by a Water-Soluble Iridium Complex Bearing a FunctionalLigand

A water-soluble iridium complex [Cp*Ir(6,6′-(OH)<sub>2</sub>-2,2′-bpy)(H<sub>2</sub>O)][OTf]<sub>2</sub> was found to be an efficient autotandem catalyst for the synthesis of secondary alcohols via redox isomerization/atmospheric hydrogenation in water. The OH groups in the bpy ligand are a key factor for the activity of the catalyst. Then, the mechanistic experiments and the practical utilization of the catalytic system were presented.

Publication Details

Journal
Figshare
Published
2025-02-13
DOI
https://doi.org/10.1021/acs.inorgchem.4c04283.s001
Primary Topic
Mycorrhizal Fungi and Plant Interactions
Type
article
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article

Auto-Tandem Catalyst: From Allylic Alcohols to SecondaryAlcohols via Redox Isomerization/Atmospheric Hydrogenation in WaterCatalyzed by a Water-Soluble Iridium Complex Bearing a FunctionalLigand

Figshare
Mycorrhizal Fungi and Plant Interactions
article

Auto-Tandem Catalyst: From Allylic Alcohols to SecondaryAlcohols via Redox Isomerization/Atmospheric Hydrogenation in WaterCatalyzed by a Water-Soluble Iridium Complex Bearing a FunctionalLigand

article en

Abstract

A water-soluble iridium complex [Cp*Ir(6,6′-(OH)<sub>2</sub>-2,2′-bpy)(H<sub>2</sub>O)][OTf]<sub>2</sub> was found to be an efficient autotandem catalyst for the synthesis of secondary alcohols via redox isomerization/atmospheric hydrogenation in water. The OH groups in the bpy ligand are a key factor for the activity of the catalyst. Then, the mechanistic experiments and the practical utilization of the catalytic system were presented.

Figshare
Clean water and sanitation
Openalex Percentile: Top 57%
Mycorrhizal Fungi and Plant Interactions
DOISourceOpenAlex
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Auto-Tandem Catalyst: From Allylic Alcohols to SecondaryAlcohols via Redox Isomerization/Atmospheric Hydrogenation in WaterCatalyzed by a Water-Soluble Iridium Complex Bearing a FunctionalLigand · Figshare (2025) | TGRS Research Map | TGRS