Onboard CarbonCapture for Circular Marine Fuels

The transition to low- and zero-carbon fuels is the primary driver for reducing emissions in the maritime industry, with methanol and natural gas emerging as the most promising options. However, carbon-based fuels will continue to emit considerable amounts of pollutants during their use phase. This work explores the application of circular economy principles in the shipping industry by integrating carbon capture and utilization technologies. Specifically, we propose a closed-loop system where carbon dioxide (CO<sub>2</sub>) generated onboard is captured using a chemical absorption technology and stored until the ship reaches a port. The captured CO<sub>2</sub> is then unloaded and transported to a fuel production facility, where it reacts with electrolytic hydrogen to regenerate the required propulsion fuel. Here, we evaluate the economic, technical, and future environmental viability of methanol and natural gas as circular marine fuels. Our findings indicate that natural gas could achieve a 65% reduction in CO<sub>2</sub> emissions by 2050, while methanol could lead to 55%, both with a 91% carbon capture rate. However, there is an economic premium of 339 USD tonCO<sub>2</sub><sup>–1</sup> for methanol and 260 USD tonCO<sub>2</sub><sup>–1</sup> for natural gas. Additionally, the shift to circular fuels is expected to increase costs by a factor of 3–6 compared to conventional operations.

Publication Details

Journal
Figshare
Published
2025-02-05
DOI
https://doi.org/10.1021/acssuschemeng.4c08354.s001
Primary Topic
Carbon Dioxide Capture Technologies
Type
article
Field-Weighted Citation Impact
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Onboard CarbonCapture for Circular Marine Fuels

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Carbon Dioxide Capture Technologies
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Onboard CarbonCapture for Circular Marine Fuels

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Abstract

The transition to low- and zero-carbon fuels is the primary driver for reducing emissions in the maritime industry, with methanol and natural gas emerging as the most promising options. However, carbon-based fuels will continue to emit considerable amounts of pollutants during their use phase. This work explores the application of circular economy principles in the shipping industry by integrating carbon capture and utilization technologies. Specifically, we propose a closed-loop system where carbon dioxide (CO<sub>2</sub>) generated onboard is captured using a chemical absorption technology and stored until the ship reaches a port. The captured CO<sub>2</sub> is then unloaded and transported to a fuel production facility, where it reacts with electrolytic hydrogen to regenerate the required propulsion fuel. Here, we evaluate the economic, technical, and future environmental viability of methanol and natural gas as circular marine fuels. Our findings indicate that natural gas could achieve a 65% reduction in CO<sub>2</sub> emissions by 2050, while methanol could lead to 55%, both with a 91% carbon capture rate. However, there is an economic premium of 339 USD tonCO<sub>2</sub><sup>–1</sup> for methanol and 260 USD tonCO<sub>2</sub><sup>–1</sup> for natural gas. Additionally, the shift to circular fuels is expected to increase costs by a factor of 3–6 compared to conventional operations.

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Life below water
Openalex Percentile: Top 55%
Carbon Dioxide Capture Technologies
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