<i>N</i>,<i>N</i>‑DisubstitutedAnilines Synthesis through Smiles Rearrangement

Herein, we report a general and mild approach to effectively synthesize N-substituted anilines under metal-free conditions using sulfonyl chlorides and amines. Notably, this approach has shown a wide array of functional group tolerance, operational simplicity, and scalability, making it a useful tool for accessing <i>N</i>,<i>N</i>-disubstituted anilines and functionalized products.