A Catalytic\nEnantioselective Suzuki Coupling for the\nModular Construction of Axially Chiral BODIPYs with Bright Solid-State\nEmission

The development of chiral BODIPYs attracts remarkable\ninterest\ndue to their unique properties, structural diversity, and good photochemical\nstability, whereas achieving the construction of chiral BODIPYs maintains\nscarce. Herein, we present an enantioselective synthesis of axially\nchiral BODIPYs through Suzuki-Miyaura coupling. The newly synthesized\nchiral BODIPYs and the coassembly showed desirable photophysical properties,\nincluding high fluorescence quantum yields and intense CPL, both in\nsolution and the solid state.