An ActivatableNIR Yb<sub>4</sub>Zn<sub>2</sub> Clusterfor the Detection of Quercetin: Analysis of Host–Guest Interactionand Sensing Mechanism

A rod-like Yb<sub>4</sub>Zn<sub>2</sub> nanocluster was constructed, which could be an activatable NIR probe for quercetin, with a short response time (5 s) and a low detection limit (0.75 μM). Theoretical simulations reveal that strong π···π interactions and hydrogen bonding result in good orbital overlap for charge transfer from quercetin to the cluster.

Publication Details

Journal
Figshare
Published
2025-03-10
DOI
https://doi.org/10.1021/acs.inorgchem.4c05572.s001
Primary Topic
Inorganic Chemistry and Materials
Type
article
Field-Weighted Citation Impact
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article

An ActivatableNIR Yb4Zn2 Clusterfor the Detection of Quercetin: Analysis of Host–Guest Interactionand Sensing Mechanism

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Inorganic Chemistry and Materials
article

An ActivatableNIR Yb4Zn2 Clusterfor the Detection of Quercetin: Analysis of Host–Guest Interactionand Sensing Mechanism

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Abstract

A rod-like Yb<sub>4</sub>Zn<sub>2</sub> nanocluster was constructed, which could be an activatable NIR probe for quercetin, with a short response time (5 s) and a low detection limit (0.75 μM). Theoretical simulations reveal that strong π···π interactions and hydrogen bonding result in good orbital overlap for charge transfer from quercetin to the cluster.

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Openalex Percentile: Top 63%
Inorganic Chemistry and Materials
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An ActivatableNIR Yb<sub>4</sub>Zn<sub>2</sub> Clusterfor the Detection of Quercetin: Analysis of Host–Guest Interactionand Sensing Mechanism · Figshare (2025) | TGRS Research Map | TGRS