Three Casesof Borates with Different DimensionalFrameworks Induced by Metal Cations

Three new metal borates containing d<sup>10</sup> cations, namely, Li<sub>4</sub>PbZn<sub>3</sub>B<sub>12</sub>O<sub>24</sub>, Na<sub>2</sub>Cd<sub>2</sub>B<sub>8</sub>O<sub>15,</sub> and K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub>, were synthesized using the flux method. K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub> is the first Zn-containing borate carbonate and has an unprecedented fundamental building block, [B<sub>10</sub>O<sub>22</sub>]. Furthermore, experimental and first-principles theoretical studies were performed.

Publication Details

Journal
Figshare
Published
2025-03-06
DOI
https://doi.org/10.1021/acs.inorgchem.5c00066.s001
Primary Topic
Crystal Structures and Properties
Type
article
Field-Weighted Citation Impact
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article

Three Casesof Borates with Different DimensionalFrameworks Induced by Metal Cations

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Crystal Structures and Properties
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Three Casesof Borates with Different DimensionalFrameworks Induced by Metal Cations

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Abstract

Three new metal borates containing d<sup>10</sup> cations, namely, Li<sub>4</sub>PbZn<sub>3</sub>B<sub>12</sub>O<sub>24</sub>, Na<sub>2</sub>Cd<sub>2</sub>B<sub>8</sub>O<sub>15,</sub> and K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub>, were synthesized using the flux method. K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub> is the first Zn-containing borate carbonate and has an unprecedented fundamental building block, [B<sub>10</sub>O<sub>22</sub>]. Furthermore, experimental and first-principles theoretical studies were performed.

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Crystal Structures and Properties
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Three Casesof Borates with Different DimensionalFrameworks Induced by Metal Cations · Figshare (2025) | TGRS Research Map | TGRS