Synthesis of 6-<i>oxa</i>-Spiro[4.5]decane\nDerivatives by Merging Ring-Opening of Benzo[<i>c</i>]oxepines\nand Formal 1,2-Oxygen Migration

A facile one-pot synthetic method has been developed\nfor constructing\n6-<i>oxa</i>-spiro[4.5]decane skeletons by merging the ring-opening\nof benzo[<i>c</i>]oxepines and formal 1,2-oxygen migration\nreactions. More than 30 examples of the 6-<i>oxa</i>-spiro[4.5]decane\nderivatives have been synthesized under transition-metal-free conditions.

Publication Details

Journal
Figshare
Published
2024-10-16
DOI
https://doi.org/10.1021/acs.joc.4c02206.s001
Primary Topic
Metal-Catalyzed Oxygenation Mechanisms
Type
article
Field-Weighted Citation Impact
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article

Synthesis of 6-oxa-Spiro[4.5]decane\nDerivatives by Merging Ring-Opening of Benzo[c]oxepines\nand Formal 1,2-Oxygen Migration

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Metal-Catalyzed Oxygenation Mechanisms
article

Synthesis of 6-oxa-Spiro[4.5]decane\nDerivatives by Merging Ring-Opening of Benzo[c]oxepines\nand Formal 1,2-Oxygen Migration

article en

Abstract

A facile one-pot synthetic method has been developed\nfor constructing\n6-<i>oxa</i>-spiro[4.5]decane skeletons by merging the ring-opening\nof benzo[<i>c</i>]oxepines and formal 1,2-oxygen migration\nreactions. More than 30 examples of the 6-<i>oxa</i>-spiro[4.5]decane\nderivatives have been synthesized under transition-metal-free conditions.

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Metal-Catalyzed Oxygenation Mechanisms
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