ManagingAmmonia for Multiple Benefits Based on VerifiedHigh-Resolution Emission Inventory in China

Atmospheric ammonia (NH₃) has multiple impacts on the environment, climate change, and human health. China is the largest emitter of NH₃ globally, with the dynamic inventory of NH₃ emissions remaining uncertain. Here, we use the second national agricultural pollution source censuses, integrated satellite data, ¹⁵N isotope source apportionment, and multiple models to better understand those key features of NH₃ emissions and its environmental impacts in China. Our results show that the total NH₃ emissions were estimated to be 11.2 ± 1.1 million tonnes in 2020, with three emission peaks in April, June, and October, primarily driven by agricultural sources, which contributed 74% of the total emissions. Furthermore, employing a series of quantitative analyses, we estimated the contribution of NH₃ emissions to ecosystem impacts. The NH₃ emissions have contributed approximately 22% to secondary PM_2.5 formation and a 16.6% increase in nitrogen loading of surface waters, while ammonium deposition led to a decrease in soil pH by 0.0032 units and an increase in the terrestrial carbon sink by 44.6 million tonnes in 2020. Reducing agricultural NH₃ emissions in China would contribute to the mitigation of air and water pollution challenges, saving damage costs estimated at around 22 billion US dollars due to avoided human and ecosystem health impacts.