I. Studies of Some Absorption Spectra in the Photographic Infrared. II. Studies of the Hydrogen Bond. III. The Raman Spectra of CCl₂F-CClF₂ and CClF₂-CClF₂

Absorption of formaldehyde and difluoro-methane under low dispersion in the photographic infra-red region is described, and approximate vibrational assignments made. An attempt was made to study some of the bands of difluoro-methane under high dispersion, but does not yield much information. The C-H band of formic acid monomer photographed under high dispersion is discussed. It has the same rotational structure as the 0-E bands. The small moment of inertia is calculated. for the third C-H vibrational state, and the band origin located.

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Publication Details

Journal
Caltech Library
Published
2025-03-13
DOI
https://doi.org/10.7907/216h-k397
Primary Topic
Molecular Spectroscopy and Structure
Type
article
Field-Weighted Citation Impact
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article

I. Studies of Some Absorption Spectra in the Photographic Infrared. II. Studies of the Hydrogen Bond. III. The Raman Spectra of CCl₂F-CClF₂ and CClF₂-CClF₂

Caltech Library
Molecular Spectroscopy and Structure
article

I. Studies of Some Absorption Spectra in the Photographic Infrared. II. Studies of the Hydrogen Bond. III. The Raman Spectra of CCl₂F-CClF₂ and CClF₂-CClF₂

article en

Abstract

Absorption of formaldehyde and difluoro-methane under low dispersion in the photographic infra-red region is described, and approximate vibrational assignments made. An attempt was made to study some of the bands of difluoro-methane under high dispersion, but does not yield much information. The C-H band of formic acid monomer photographed under high dispersion is discussed. It has the same rotational structure as the 0-E bands. The small moment of inertia is calculated. for the third C-H vibrational state, and the band origin located.

Caltech Library
California Institute of Technology (US)
Openalex Percentile: Top 60%
Molecular Spectroscopy and Structure
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