Dichloromethyl(diaryl)Sulfonium Salts as <i>gem</i>-Dichlorocyclopropanation Reagents

<i>gem</i>-Dichlorocyclopropanes are important structural moieties in a range of industrial sectors and have been the focus of considerable interest within the synthetic community over the years. Synthetic methodologies to access <i>gem</i>-dichlorocyclopropanes, however, remain limited. To address this challenge, we report the development of new dichloromethyl(diaryl) sulfonium salts as reagents for the <i>gem</i>-dichlorocyclopropanation of electron-rich olefins via a free dichlorocarbene pathway under mild conditions in yields of up to 70%. This methodology provides access to previously unreported <i>gem</i>-dichlorocyclopropanes.