Characterization of the thermoluminescence glow curve of Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>:Cu,Ag

This work presents the characterization of the thermoluminescence (TL) glow curve of a copper and silver doped lithium tetraborate (Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>:Cu,Ag) made using three different methods to identify the number of peaks, the trap structure and the kinetics parameters: T<sub>M</sub>-T<sub>stop</sub>, glow curve fitting (GCF) and various heating rates (VHR). The obtained results can be consistently explained assuming four TL glow peaks in the region 50 - 270 °C, originated by a complex trap structure: continuous energy distributions for peaks I, III and IV, and general order kinetics (GOK) discrete trapping level for peak II. Quite similar activation energy values have been obtained by GCF and VHR methods.

Publication Details

Journal
Figshare
Published
2024-12-13
DOI
https://doi.org/10.6084/m9.figshare.28025000
Primary Topic
Luminescence Properties of Advanced Materials
Type
article
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article

Characterization of the thermoluminescence glow curve of Li2B4O7:Cu,Ag

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Luminescence Properties of Advanced Materials
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Characterization of the thermoluminescence glow curve of Li2B4O7:Cu,Ag

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Abstract

This work presents the characterization of the thermoluminescence (TL) glow curve of a copper and silver doped lithium tetraborate (Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>:Cu,Ag) made using three different methods to identify the number of peaks, the trap structure and the kinetics parameters: T<sub>M</sub>-T<sub>stop</sub>, glow curve fitting (GCF) and various heating rates (VHR). The obtained results can be consistently explained assuming four TL glow peaks in the region 50 - 270 °C, originated by a complex trap structure: continuous energy distributions for peaks I, III and IV, and general order kinetics (GOK) discrete trapping level for peak II. Quite similar activation energy values have been obtained by GCF and VHR methods.

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Characterization of the thermoluminescence glow curve of Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>:Cu,Ag · Figshare (2024) | TGRS Research Map | TGRS