Improving corrosion resistance of Kovar by subjection to a coupled electromagnetic treatment

As a common electronic packaging device, Kovar primarily serves to secure, seal, and protect semiconductor chips. The Ni–Au coating applied to its surface effectively resists external corrosion. However, residual stress and defects generated during the electroplating process of the Ni–Au layer often diminish the corrosion resistance of the coating. This study employs a coupled electromagnetic treatment (CEMT) to regulate the Ni–Au coating after electroplating, with the aim of improving their corrosion resistance. The results indicate that the corrosion resistance of the Ni–Au coating was effectively improved after CEMT, and the product qualification rate is 95 %. The residual tensile stress was greatly reduced, the residual tensile stress in the X direction was reduced by 44.84 %, and in the Y direction was reduced by 61.75 %. The nanohardness increased from 0.74 GPa to 0.91 GPa, an increase of 22.97 %. Microstructure analysis showed that the dislocation density of the coating after CEMT was reduced by about 4.2 %, and the dislocation distribution was more uniform. The reduction of stress and the repair of defects provide an important basis for improving the corrosion resistance of the coating.

Publication Details

Journal
Strathprints: The University of Strathclyde institutional repository (University of Strathclyde)
Published
2025-01-01
DOI
https://doi.org/10.17868/strath.00093331
Primary Topic
Electromagnetic Effects on Materials
Type
article
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article

Improving corrosion resistance of Kovar by subjection to a coupled electromagnetic treatment

Strathprints: The University of Strathclyde institutional repository (University of Strathclyde)
Electromagnetic Effects on Materials
article

Improving corrosion resistance of Kovar by subjection to a coupled electromagnetic treatment

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Abstract

As a common electronic packaging device, Kovar primarily serves to secure, seal, and protect semiconductor chips. The Ni–Au coating applied to its surface effectively resists external corrosion. However, residual stress and defects generated during the electroplating process of the Ni–Au layer often diminish the corrosion resistance of the coating. This study employs a coupled electromagnetic treatment (CEMT) to regulate the Ni–Au coating after electroplating, with the aim of improving their corrosion resistance. The results indicate that the corrosion resistance of the Ni–Au coating was effectively improved after CEMT, and the product qualification rate is 95 %. The residual tensile stress was greatly reduced, the residual tensile stress in the X direction was reduced by 44.84 %, and in the Y direction was reduced by 61.75 %. The nanohardness increased from 0.74 GPa to 0.91 GPa, an increase of 22.97 %. Microstructure analysis showed that the dislocation density of the coating after CEMT was reduced by about 4.2 %, and the dislocation distribution was more uniform. The reduction of stress and the repair of defects provide an important basis for improving the corrosion resistance of the coating.

Strathprints: The University of Strathclyde institutional repository (University of Strathclyde)
Openalex Percentile: Top 58%
Electromagnetic Effects on Materials
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Improving corrosion resistance of Kovar by subjection to a coupled electromagnetic treatment · Strathprints: The University of Strathclyde institutional repository (University of Strathclyde) (2025) | TGRS Research Map | TGRS