Optimal Operating Windows for CO₂ Capturein Lithium–Sodium Borates: Phase Transition and CompositionEffects

Alkali metal borate molten salts have emerged as efficient high-temperature liquid CO₂ sorbents, advancing carbon reduction for energy-intensive industrial chemical processes. This work investigated the relationship between the liquidus behavior and CO₂ uptake characteristics of lithium–sodium borates, M_<i>x</i>B_1–<i>x</i>O_{1.5–<i>x</i>} (M = Li_0.5Na_0.5), over a composition range of 0.50 ≤ <i>x</i> ≤ 0.80. Differential Scanning Calorimetry (DSC) measurements revealed detailed phase–transition profiles, with liquidus temperatures ranging from 500 to 650 °C. Composition-dependent liquidus behavior governs the CO₂ sorption characteristics during the early sorption stages, transitioning from “solid-to-liquid” in low-alkali to “liquid-to-liquid” in high-alkali regions. Optimal working capacities and reaction rates consistently correspond to the liquidus transition range, minimizing energy demands for preserving molten state in the cyclic CO₂ capture-release operations. These findings establish temperature–composition operating windows tailored to industrial needs, providing critical liquidus diagrams and demonstrating their potential as versatile sorbents for high-temperature CO₂ capture.