Atomically Sharp\n1D Interfaces in 2D Lateral Heterostructures\nof VSe<sub>2</sub>NbSe<sub>2</sub> Monolayers

van der Waals heterostructures have emerged as an ideal\nplatform\nfor creating engineered artificial electronic states. While vertical\nheterostructures have been extensively studied, realizing high-quality\nlateral heterostructures with atomically sharp interfaces remains\na major experimental challenge. Here, we advance a one-pot two-step\nmolecular beam lateral epitaxy approach and successfully synthesize\natomically well-defined 1T-VSe<sub>2</sub>1H-NbSe<sub>2</sub> lateral heterostructures. We demonstrate the formation of defect-free\nlateral heterostructures and characterize their electronic structure\nby using scanning tunneling microscopy and spectroscopy together with\ndensity functional theory calculations. We find additional electronic\nstates at the 1D interface as well as signatures of Kondo resonances\nin a side-coupled geometry. Our experiments explored the full potential\nof lateral heterostructures for realizing exotic electronic states\nin low-dimensional systems for further studies of artificial designer\nquantum materials.

Publication Details

Journal
Figshare
Published
2024-11-02
DOI
https://doi.org/10.1021/acsnano.4c10302.s001
Primary Topic
Topological Materials and Phenomena
Type
article
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Atomically Sharp\n1D Interfaces in 2D Lateral Heterostructures\nof VSe2NbSe2 Monolayers

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Topological Materials and Phenomena
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Atomically Sharp\n1D Interfaces in 2D Lateral Heterostructures\nof VSe2NbSe2 Monolayers

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Abstract

van der Waals heterostructures have emerged as an ideal\nplatform\nfor creating engineered artificial electronic states. While vertical\nheterostructures have been extensively studied, realizing high-quality\nlateral heterostructures with atomically sharp interfaces remains\na major experimental challenge. Here, we advance a one-pot two-step\nmolecular beam lateral epitaxy approach and successfully synthesize\natomically well-defined 1T-VSe<sub>2</sub>1H-NbSe<sub>2</sub> lateral heterostructures. We demonstrate the formation of defect-free\nlateral heterostructures and characterize their electronic structure\nby using scanning tunneling microscopy and spectroscopy together with\ndensity functional theory calculations. We find additional electronic\nstates at the 1D interface as well as signatures of Kondo resonances\nin a side-coupled geometry. Our experiments explored the full potential\nof lateral heterostructures for realizing exotic electronic states\nin low-dimensional systems for further studies of artificial designer\nquantum materials.

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Topological Materials and Phenomena
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Atomically Sharp\n1D Interfaces in 2D Lateral Heterostructures\nof VSe<sub>2</sub>NbSe<sub>2</sub> Monolayers · Figshare (2024) | TGRS Research Map | TGRS