Oxygen-Vacancy-RichSnO<sub>2</sub> NanoparticlesBased Ultralow-Power MEMS Sensor for Nitrogen Dioxide Detection

The development of highly sensitive and ultralow-power NO<sub>2</sub> sensors is crucial for real-time NO<sub>2</sub> monitoring. This study synthesizes tiny SnO<sub>2</sub> nanoparticles with enriched oxygen vacancies for use in microelectromechanical system (MEMS) gas sensors, enabling ppb-level NO<sub>2</sub> detection at reduced operating temperatures. PVP was used to adjust the particle size and surface oxygen vacancies in the hydrothermal method. The gas sensing performance shows that the 0.75 g PVP-SnO<sub>2</sub> exhibited the highest response of 14.7 to 500 ppb NO<sub>2</sub> at a low operating temperature of 102 °C, which is 3.2 times higher than that of the 0.00 g PVP-SnO<sub>2</sub> sensor under the same conditions. Compared to similar studies, this sensor achieved a high response value and ultralow power consumption of 8.4 mW. The improvement in performance is mainly attributed to N doping and the abundance of oxygen vacancies. This research presents a promising strategy for the development of high-performance, low-energy, real-time NO<sub>2</sub> gas sensors.

Publication Details

Journal
Figshare
Published
2025-03-27
DOI
https://doi.org/10.1021/acsanm.4c06932.s001
Primary Topic
Gas Sensing Nanomaterials and Sensors
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article
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article

Oxygen-Vacancy-RichSnO2 NanoparticlesBased Ultralow-Power MEMS Sensor for Nitrogen Dioxide Detection

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Gas Sensing Nanomaterials and Sensors
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Oxygen-Vacancy-RichSnO2 NanoparticlesBased Ultralow-Power MEMS Sensor for Nitrogen Dioxide Detection

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Abstract

The development of highly sensitive and ultralow-power NO<sub>2</sub> sensors is crucial for real-time NO<sub>2</sub> monitoring. This study synthesizes tiny SnO<sub>2</sub> nanoparticles with enriched oxygen vacancies for use in microelectromechanical system (MEMS) gas sensors, enabling ppb-level NO<sub>2</sub> detection at reduced operating temperatures. PVP was used to adjust the particle size and surface oxygen vacancies in the hydrothermal method. The gas sensing performance shows that the 0.75 g PVP-SnO<sub>2</sub> exhibited the highest response of 14.7 to 500 ppb NO<sub>2</sub> at a low operating temperature of 102 °C, which is 3.2 times higher than that of the 0.00 g PVP-SnO<sub>2</sub> sensor under the same conditions. Compared to similar studies, this sensor achieved a high response value and ultralow power consumption of 8.4 mW. The improvement in performance is mainly attributed to N doping and the abundance of oxygen vacancies. This research presents a promising strategy for the development of high-performance, low-energy, real-time NO<sub>2</sub> gas sensors.

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