Flower-like WO<sub>3</sub> Nanorod Structures Modified\nwith MoS<sub>2</sub> Quantum Dots for Low-Temperature Acetone Detection

As a prevalent volatile organic compound (VOC), acetone\nplays a\nsignificant role in diverse domains, such as environmental protection,\nindustrial production, and medical diagnosis. However, if acetone\nis not adequately monitored and disposed of, it can result in immeasurable\nadverse effects on human health and the natural environment. Therefore,\nit is essential to realize the highly sensitive, convenient, and efficient\nreal-time detection of acetone. In this study, MoS<sub>2</sub> quantum\ndots (QDs) were modified on flower-like WO<sub>3</sub> nanorod structure\nthrough the hydrothermal approach to fabricate a WO<sub>3</sub>/MoS<sub>2</sub> sensor. The sensing performance of the sensor for acetone\nwas investigated. The results showed that the sensor had a response\nvalue of 14.96 for 30 ppm of acetone gas at optimum operating temperature\n(132 °C), which was 3.2 times the performance of a pure WO<sub>3</sub> gas sensor. The response of the WO<sub>3</sub>/MoS<sub>2</sub> sensor was reduced by only 20% under a relative humidity of 85%.\nBesides, the sensor still maintained a high response (11.25 for 30\nppm) under high curvature conditions (120°). Finally, the sensitization\neffects of MoS<sub>2</sub> QDs, including the formation of n-n heterojunction\nwith WO<sub>3</sub> and the catalytic overflow of oxygen species,\nwere discussed in detail. This study provides a valuable reference\nfor the construction of low-temperature and high-performance gas sensors\nbased on QD-sensitized metal oxide nanomaterials.

Publication Details

Journal
Figshare
Published
2024-12-05
DOI
https://doi.org/10.1021/acsanm.4c06344.s001
Primary Topic
Gas Sensing Nanomaterials and Sensors
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article
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Flower-like WO3 Nanorod Structures Modified\nwith MoS2 Quantum Dots for Low-Temperature Acetone Detection

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Gas Sensing Nanomaterials and Sensors
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Flower-like WO3 Nanorod Structures Modified\nwith MoS2 Quantum Dots for Low-Temperature Acetone Detection

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Abstract

As a prevalent volatile organic compound (VOC), acetone\nplays a\nsignificant role in diverse domains, such as environmental protection,\nindustrial production, and medical diagnosis. However, if acetone\nis not adequately monitored and disposed of, it can result in immeasurable\nadverse effects on human health and the natural environment. Therefore,\nit is essential to realize the highly sensitive, convenient, and efficient\nreal-time detection of acetone. In this study, MoS<sub>2</sub> quantum\ndots (QDs) were modified on flower-like WO<sub>3</sub> nanorod structure\nthrough the hydrothermal approach to fabricate a WO<sub>3</sub>/MoS<sub>2</sub> sensor. The sensing performance of the sensor for acetone\nwas investigated. The results showed that the sensor had a response\nvalue of 14.96 for 30 ppm of acetone gas at optimum operating temperature\n(132 °C), which was 3.2 times the performance of a pure WO<sub>3</sub> gas sensor. The response of the WO<sub>3</sub>/MoS<sub>2</sub> sensor was reduced by only 20% under a relative humidity of 85%.\nBesides, the sensor still maintained a high response (11.25 for 30\nppm) under high curvature conditions (120°). Finally, the sensitization\neffects of MoS<sub>2</sub> QDs, including the formation of n-n heterojunction\nwith WO<sub>3</sub> and the catalytic overflow of oxygen species,\nwere discussed in detail. This study provides a valuable reference\nfor the construction of low-temperature and high-performance gas sensors\nbased on QD-sensitized metal oxide nanomaterials.

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Flower-like WO<sub>3</sub> Nanorod Structures Modified\nwith MoS<sub>2</sub> Quantum Dots for Low-Temperature Acetone Detection · Figshare (2024) | TGRS Research Map | TGRS